The activation energy of a reaction can be determined from the slope of the graph between :
1. ln K vs T
2. ln vs T
3. ln K vs
4.
If the half-life is independent of its initial concentration, then the order of the reaction is:
1. 0
2. 1
3. 3
4. 2
The rate constant of the reaction A B is 0.6 x 10-3 molar per second. If the
concentration of A is 5 M then concentration of B after 20 min is
1. 1.08 M
2. 3.60 M
3. 0.36 M
4. 0.72 M
If the rate of reaction doubles when the temperature is raised from 20 °C to 35 °C, then the activation energy for the reaction will be :
(R = 8.314 J mol-1 K-1)
1. 342 kJ mol-1
2. 269 kJ mol-1
3. 34.7 kJ mol-1
4. 15.1 kJ mol-1
A reaction having equal energies of activation for forward and reverse reactions has
1. S = 0
2. G = 0
3. H = 0
4. H = G = S = 0
For the reaction,
N2O5(g) → 2NO2(g) + \(\frac{1}{2}\)O2(g)
the value of the rate of disappearance of is given as . The rate of formation of is given respectively as:
1. 6.25 x 10-3 mol L-1s-1 and 6.25 x 10-3 mol L-1s-1
2. 1.25 x 10-2 mol L-1s-1 and 3.125 x 10-3 mol L-1s-1
3. 6.25 x 10-3 mol L-1s-1 and 3.125 x 10-3 mol L-1s-1
4. 1.25 x 10-2 mol L-1s-1 and 6.25 x 10-3 mol L-1s-1
For an endothermic reaction, energy of activation is Ea and enthalpy of reaction is H (both of these in kJ/mol). Minimum value of Ea will be
1. Less than H
2. Equal to H
3. More than H
4. Equal to zero
Half-life period of a first order reaction is 1386s. The specific rate constant of the reaction
is
1. 5.0 x 10-3s-1
2. 0.5 x 10-2s-1
3. 0.5 x 10-3s-1
4. 5.0 x 10-2s-1
For the reaction A+B products, it is observed that
(1) | On doubling the initial concentration of A only, the rate of reaction is also doubled and |
(2) | On doubling the initial concentrations of both A and B, there is a change by a factor of 8 in that rate of the reaction |
The rate of this reaction is, given by
1. rate = k[A]2[B]
2. rate = k[A][B]2
3. rate = k[A]2[B]2
4. rate = k[A][B]
In the reaction, BrO-3(aq) + 5Br-(aq) + 6H+ 3Br2(l) + 2H2O(l)
The rate of appearance of bromine (Br2) is related to rate of disappearance of bromide
ions as following
1. d[Br2]/dt = -(3/5)d[Br-]/dt
2. d[Br2]/dt = (5/3)d[Br-]/dt
3. d[Br2]/dt = -(5/3)d[Br-]/dt
4. d[Br2]/dt = (3/5)d[Br-]/dt