Calculate the molality of a solution of H₂SO₄ having specific gravity 1.98 g mL⁻¹ and composition 95% (w/v)

(1) 7.412

(2) 8.412

(3) 9.412

(4) 10.412

Subtopic:  Concentration Terms & Henry's Law |
 65%
Level 2: 60%+
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A solution contains 16 gm of methanol and 90 gm of water, mole fraction of methanol is

(1) 0.90

(2) 0.090

(3) 0.1

(4) 1.9

Subtopic:  Concentration Terms & Henry's Law |
 76%
Level 2: 60%+
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Lowering in vapour pressure is the highest for:

1. 0.2 m urea

2. 0.1 m glucose

3. 0.1 m MgSO4

4. 0.1 m BaCl2

Subtopic:  Relative Lowering of Vapour Pressure |
 73%
Level 2: 60%+
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The Vapour pressure of CCl4 at 25°C is 143 mm Hg. 0.5 g of a non-volatile solute (mol. wt. 65) is dissolved in 100 ml of CCl4. The vapor pressure of the solution is:

(Density of CCl= 1 .58 g/cm3)

1. 141.93 mm Hg

2. 94.39 mm Hg

3. 199.34 mm Hg

4. 143.99 mm Hg

Subtopic:  Relative Lowering of Vapour Pressure |
 68%
Level 2: 60%+
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The vapour pressure of pure benzene and toluene are 160 and 60 torr respectively. The mole fraction of toluene in vapour phase in contact with an equimolar solution of benzene and toluene is -

1. 0.50 2. 0.6
3. 0.27 4. 0.73
Subtopic:  Dalton’s Law of Partial Pressure |
 64%
Level 2: 60%+
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Find the molar concentration (in mol L⁻¹) of a solution whose osmotic pressure is 0.0821 atm at 300 K.

(1) 0.033

(2) 0.066

(3) 0.33 × 10–2

(4) 3.0

Subtopic:  Osmosis & Osmotic Pressure |
 85%
Level 1: 80%+
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The osmotic pressure of 5 % (mass-volume) solution of cane sugar at 150 °C (mol. mass of sugar = 342 g/mole) is:

1. 4 atm 2. 5.07 atm
3. 3.55 atm 4. 2.45 atm
Subtopic:  Osmosis & Osmotic Pressure |
 79%
Level 2: 60%+
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A solution containing 3.3 g of a substance in 125 g of benzene (b.p. 80°C) boils at 80.66°C. If Kb for one litre of benzene is 3.28°C, the molecular weight of the substance shall be 

1. 127.20

2. 131.20

3. 137.12

4. 142.72

Subtopic:  Elevation of Boiling Point |
 77%
Level 2: 60%+
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An aqueous solution containing 1 g of urea boils at 100.25 °C. The aqueous solution containing 3 g of glucose in the same volume will boil at:
1. 100.75 °C
2. 100.5 °C
3. 100 °C
4. 100.25 °C

Subtopic:  Osmosis & Osmotic Pressure |
 75%
Level 2: 60%+
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Solution of sucrose (Mol. Mass = 342) is prepared by dissolving 34.2 gm of it in 1000 gm of water. Freezing point of the solution is (Kf for water is 1.86 K kg mol–1) [AIEEE 2003]

(1) 272.814 K

(2) 278.1 K

(3) 273.15 K

(4) 270 K

Subtopic:  Depression of Freezing Point |
 76%
Level 2: 60%+
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