H₂SO₄ solution whose specific gravity is 1.98 g ml^–1 and H₂SO₄ by volume is 95% (w/v). The molality of the solution will be

(1) 7.412

(2) 8.412

(3) 9.412

(4) 10.412

A solution contains 16 gm of methanol and 90 gm of water, mole fraction of methanol is

(1) 0.90

(2) 0.090

(3) 0.1

(4) 1.9

Lowering in vapour pressure is the highest for:

1. 0.2 m urea

2. 0.1 m glucose

3. 0.1 m MgSO₄

4. 0.1 m BaCl₂

The Vapour pressure of CCl₄ at 25°C is 143 mm Hg. 0.5 g of a non-volatile solute (mol. wt. 65) is dissolved in 100 ml of CCl₄. The vapor pressure of the solution is-

(Density of CCl₄ = 1 .58 g/cm³$)$ 

1. 141.93 mm Hg

2. 94.39 mm Hg

3. 199.34 mm Hg

4. 143.99 mm Hg

The vapour pressure of pure benzene and toluene are 160 and 60 torr respectively. The mole fraction of toluene in vapour phase in contact with an equimolar solution of benzene and toluene is -

Osmotic pressure is 0.0821 atm at a temperature of 300 K. Find concentration in mole/litre [Roorkee 1990]

(1) 0.033

(2) 0.066

(3) 0.33 × 10^–2

(4) 3

The osmotic pressure of 5 % (mass-volume) solution of cane sugar at 150 °C (mol. mass of sugar = 342 g/mole) is:

A solution containing 3.3 g of a substance in 125 g of benzene (b.p. 80°C) boils at 80.66°C. If K_b for one litre of benzene is 3.28°C, the molecular weight of the substance shall be 

1. 127.20

2. 131.20

3. 137.12

4. 142.72

An aqueous solution containing 1 g of urea boils at 100.25 °C. The aqueous solution containing 3 g of glucose in the same volume will boil at:
1. 100.75 °C
2. 100.5 °C
3. 100 °C
4. 100.25 °C

Solution of sucrose (Mol. Mass = 342) is prepared by dissolving 34.2 gm of it in 1000 gm of water. Freezing point of the solution is (K_f for water is 1.86 K kg mol^–1) [AIEEE 2003]

(1) 272.814 K

(2) 278.1 K

(3) 273.15 K

(4) 270 K