At 25 °C molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is 9.54 Ω-1 cm2 mol-1 and at infinite dilution its molar conductance is 238 Ω-1 cm2 mol-1. The degree of ionisation of ammonium hydroxide at the same concentration and temperature is :
1. | 2.080 % | 2. | 20.800 % |
3. | 4.008 % | 4. | 40.800 % |
When a copper wire is immersed in a solution of AgNO3, the colour of the solution becomes blue because copper:
1. Forms a soluble complex with \(AgNO_3\)
2. Is oxidised to \(Cu^{2+}\)
3. Is reduced to \(Cu^{2-}\)
4. Splits up into atomic form and dissolves
The specific conductance of a 0.1 M KCl solution at 23 °C is 0.012 Ω–1 cm–1. The resistance of cells containing the solution at the same temperature was found to be 55 Ω. The cell constant will be:
1. | 0.142 cm–1 | 2. | 0.66 cm–1 |
3. | 0.918 cm–1 | 4. | 1.12 cm–1 |
Without losing it's concentration, ZnCl2 solution cannot be kept in contact with :
1. Au
2. Al
3. Pb
4. Ag
The standard reduction potential at 290 K for the following half reactions are,
(i) Zn2+ + 2e— → Zn(s); E° = -0.762 V
(ii) Cr3+ + 3e → Cr(s); E° = -0.740 V
(iii) 2H+ + 2e → H2(g); · E° = +0.000 V
(iv) Fe3+ + e → Fe2+; E° = +0.77V
Which is the strongest reducing agent?
1. Zn
2. Cr
3. Fe2+
4. H2
The Zn acts as sacrificial or cathodic protection to prevent rusting of iron because:
1. of Zn < of Fe
2. of Zn > of Fe
3. of Zn = of fe
4. Zn is cheaper than iron
What mass of copper will be deposited by passing 2 faraday of electricity through a solution of Cu(II) salt?
1. 35.6 g
2. 63.5 g
3. 6.35 g
4. 3.56 g
The same amount of electricity was passed through two cells containing molten Al2O3 and molten NaCl. If 1.8 g of Al were liberated in one cell, the amount of Na liberated in the other cell is:
1. 4.6 g
2. 2.3 g
3. 6.4 g
4. 3.2 g
The standard reduction electrode potentials of three metals X, Y, and Z are given as -1.2 V, +0.5 V, and -3.0 V, respectively. Based on these values, what is the correct order of their reducing power?
1. | Y > X >Z | 2. | Z > X > Y |
3. | X > Y > Z | 4. | Y > Z > X |
During an electrolysis experiment, if a 100 mA current is passed through a solution of AgNO3 for 30 minutes, how many coulombs of electricity will be consumed?
1. 108 C
2. 18000 C
3. 180 C
4. 3000 C