Equivalent conductances of NaCl, HCl and C2H5COONa at infinite dilution are 126.45, 426.16 and 91 Ω-1cm2. The equivalent conductance of C2H5COOH is : 

1. 201.28 Ω-1cm2

2. 390.71 Ω-1cm2

3. 698.28 Ω-1cm2

4. 540.48 Ω-1cm2

Subtopic:  Conductance & Conductivity |
 91%
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The equivalent conductance of M/32 solution of a weak monobasic acid is 8.0 mho cm2 and at infinite dilution is 400 mhocm2. The dissociation constant of the acid is

1. 1.25 x 10-5

2. 1.25 x 10-6

3. 6.25 x 10-4

4. 1.25 x 10-4

Subtopic:  Conductance & Conductivity |
 62%
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The change in reduction potential of a hydrogen electrode when its solution initialy at pH = 0 is neutralised to pH = 7, is a/an-

1. Increase by 0.059 V 2. Decrease by 0.059 V
3. Increase by 0.41 V 4. Decrease by 0.41 V
Subtopic:  Electrode & Electrode Potential | Nernst Equation |
 52%
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 The cell reaction for the given cell is spontaneous if:

Ptcl2|cl-(1M)||Cl-(1M)|PtCl2

1. P1 > P2 

2. P1 < P2

3. P1 = P2

4. P1 = 1 atm

Subtopic:  Electrode & Electrode Potential |
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Each of the three metals X, Y and Z were put in turn into aqueous solution of the other two.

X + Salt of Y (or Z)   Y (or Z) + Salt of X.

Which observation is probably incorrect?

1. Y + Salt of X = No action observed

2. Y + Salt of Z = Z + Salt of Y

3. Z + Salt of X = X + Salt of Z

4. Z + Salt of Y = No action observed

Subtopic:  Electrochemical Series |
 59%
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The standard reduction potentials of Cu2+/Cu and Cu2+/Cu+ are 0.337 and 0.153V respectively. The standard electrode potential of Cu+/Cu half cell is:

1. 0.184V 

2. 0.827V

3. 0.521V

4. 0.490V

Subtopic:  Electrode & Electrode Potential |
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When a lead storage battery is discharged, then:

1. SO2 is evolved.

2. Lead is formed.

3. Lead sulphate is consumed.

4. Sulphuric acid is consumed.

Subtopic:  Batteries & Salt Bridge |
 59%
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The molar conductances of Ba2+ and Cl- 127 and 76Ω-1 cm-1 mol-1 respectively at infinite dilution. The equivalent conductance of BaCl2 at infinite dilution will be

1. 139.52

2. 203

3. 279

4. 101.5

Subtopic:   Kohlrausch Law & Cell Constant |
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A depolariser used in dry cell batteries is: 

1. Ammonium chloride 

2. Manganese dioxide

3. Potassium hydroxide 

4. Sodium phosphate

Subtopic:  Batteries & Salt Bridge |
 52%
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The reaction taking place  at anode when an aqueous solution of CuSO4 is electrolysed using inert Pt electrode:

1. 2SO42-  S2O32- + 2e

2. Cu2+ + 2e Cu

3. 2H2 O2 + 4H+ + 4e

4. 2H+ +2e  H2

Subtopic:  Electrode & Electrode Potential |
 67%
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