In which of the following reactions, the standard reaction entropy change
$(∆S^0)$ is positive, and standard Gibb's energy change
$(∆G^0)$ decreases sharply with increasing temperature?

1.	C(graphite) + \(\frac{1}{2}\)O2(g) → CO(g)
2.	CO(g) + \(\frac{1}{2}\)O2(g) → CO2(g)
3.	Mg(s) + \(\frac{1}{2}\)O2(g) → MgO(s)
4.	\(\frac{1}{2}\)C(graphite) + \(\frac{1}{2}\)O2(g) → \(\frac{1}{2}\)CO2(g)

The enthalpy of fusion of water is 1.435 kcal/mol. The molar entropy change for the melting of ice at 0 ^oC is:

1. 10.52 cal/(mol K)

2. 21.04 cal/(mol K)

3. 5.260 cal/(mol K)

4. 0.526 cal/(mol K)

The standard enthalpy of vaporization ${∆}_{\mathrm{vap}}{\mathrm{H}}^{\mathrm{o}}$ for water at 100 ^oC is 40.66 kJ mol^–1. The internal energy of vaporization of water at 100 ^oC (in kJ mol^–1) is: 
(Assume water vapour behaves like an ideal gas.)

1. +37.56

2. –43.76

3. +43.76

4. +40.66

Identify which of the following is the correct option for free expansion of an ideal gas under adiabatic condition.

1.  $\mathrm{ \Delta q}\ne 0,$ $∆\mathrm{T}=0,$ $\mathrm{W}=0$
2.  $\mathrm{ \Delta q}=0,$ $∆\mathrm{T}=0,$ $\mathrm{W}=0$
3.  $\mathrm{ \Delta q}=0,$ $∆\mathrm{T}<0,$ $\mathrm{W}\ne 0$
4.  $\mathrm{ \Delta q}=0,$ $∆\mathrm{T}\ne 0,$ $\mathrm{W}=0$

Given the following reaction:
\(4H(g)\)→  \(2 H_{2}\)\((g)\)
The enthalpy change for the reaction is -869.6 kJ. The dissociation energy of the H-H bond is:
1. -869.6 kJ
2. +434.8kJ
3. +217.4kJ
4. -434.8 kJ

From the following bond energies:
H—H bond energy: 431.37 kJ mol^-1 
C=C bond energy: 606.10 kJ mol^-1 
C—C bond energy: 336.49 kJ mol^-1 
C—H bond energy: 410.50 kJ mol^-1 
Enthalpy for the reaction, 

will be:

The values of ΔH and ΔS for the given reaction are 170 kJ and 170 JK^-1, respectively.
C_(graphite) + CO₂(g)→2CO(g) 
This reaction will be spontaneous at:

1. 710 K
2. 910 K
3. 1110 K
4. 510 K