Which one of the following ions is the most stable in an aqueous solution?
(At. No. Ti = 22, V = 23, Cr = 24, Mn = 25)
1. \(\text{Cr}^{3 +}\)
2. \(\text V^{3 +}\)
3. \(\text{Ti}^{3 +}\)
4. \(\text{Mn}^{3 +}\)
The d-electron configurations of Cr2+, Mn2+, Fe2+ and Ni2+ and 3d4, 3d5, 3d6 and 3d8 respectively.
Which one of the following aqua complexes will exhibit the minimum paramagnetic behaviour?
(At. No. Cr = 24, Mn = 25, Fe = 26, Ni = 28)
1. \(\left[\mathrm{Mn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}\)
2. \(\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}\)
3. \(\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}\)
4. \(\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}\)
The manganate and permanganate ions are tetrahedral, due to:
1. | The π-bonding involves the overlap of d-orbitals of oxygen with d-orbitals of manganese. |
2. | The π-bonding involves the overlap of p-orbitals of oxygen with d-orbitals of manganese. |
3. | Absence of π-bonding. |
4. | The π-bonding involves the overlap of p-orbitals of oxygen with p-orbitals of manganese. |
Which one of the elements with the following outer orbital configurations may exhibit the largest number of oxidation states?
1. 3d3, 4s2
2. 3d5, 4s1
3. 3d5, 4s2
4. 3d2, 4s2
Which of the following pairs has the same size?
1.
2.
3.
4.
Which one of the following ions has electronic configuration [Ar] 3d6?
(At. no :Mn = 25, Fe= 26, Co= 27, Ni = 28)
1.
2.
3.
4.
Which of the following ions will exhibit colour in aqueous solutions?
1. La3+ (Z=57)
2. Ti3+ (Z=22)
3. Lu3+ (Z=71)
4. Sc3+ (Z=21)
Acidified K2Cr2O7 solution turns green when Na2SO3 is added to it. This is due to the formation of:
1.
2.
3.
4.
1. | The greater metallic character of the lanthanoids than that of the corresponding actinoids. |
2. | More energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals. |
3. | The lesser energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals. |
4. | More active nature of the actinoids. |
For the four successive transition elements (Cr, Mn, Fe and Co), the stability of +2 oxidation state will be there in which of the following order?
(At. No Cr= 24, Mn= 25, Fe=26, Co= 27)
1. Fe>Mn>Co>Cr
2. Co>Mn>Fe>Cr
3. Cr>Mn>Co>Fe
4. Mn>Fe>Cr>Co