The same amount of electricity was passed through two cells containing molten Al2O3 and molten NaCl. If 1.8g of Al were liberated in one cell, the amount of Na liberated in the other cell is:
(1) 4.6 g
(2) 2.3 g
(3) 6.4 g
(4) 3.2 g
Standard Reduction electrode potential of three metals X, Y and Z are -1.2V, + 0.5V and -3V respectively. The reducing power of these metals will be
(1) Y>X>Z
(2) Z>X>Y
(3) X>Y>Z
(4) Y>Z>X
How many columbs of electricity are consumed when 100 mA current is passed through a solution of AgNO3 for 30 minute during an electrolysis experiment?
(1) 108
(2) 18000
(3) 180
(4) 3000
Standard reduction potentials at 25C of Li+/Li, Ba2+/Ba, Na+/Na and Mg2+/Mg are -3.05, -2.90, -2.71 and -2.37 V respectively. Which one of the following is the strongest oxidising agent ?
(1) Mg2+
(2) Ba2+
(3) Na+
(4) Li+
For the cell, Ti/Ti+(0.001M)||Cu2+(0.1M)|Cu, at
25 C is 0.83 V. Ecell can be increased :
1. By increasing [Cu2+]
2. By increasing [Ti+]
3. By decreasing [Cu2+]
4. None of the above.
A hydrogen gas electrode is made by dipping platinum wire in a solution of HCI of pH = 10 and by passing hydrogen gas around the platinum wire at 1 atm pressure. The oxidation potential of electrode would be
1. 0.059 V
2. 0.59 V
3. 00.118 V
4. 1.18 V
The atomic mass of Al is 27. When a current of 5 faraday is passed through a solution of Al3+ ions, the mass of Al deposited is:
(1) 27g
(2) 36g
(3) 45g
(4) 9g
On the basis of the information available from the reaction.
of O2, the minimum EMF required to carry out the electrolysis of Al2O3 is :(F=96500 C mol-1)
(1) 2.14 V
(2) 4.28 V
(3) 6.42 V
(4) 8.56 V
For the reduction of silver ions with copper metal, the standard cell potential was found to be + 0.46 V at 25ºC. The value of standard Gibbs energy, G0 will be:
(F = 96500 Cmol-1)
1. -89.0 KJ
2. 89.0 J
3. -44.5 KJ
4. -98.0 KJ
A solution of sodium sulphate in water is electrolysed using inert electrodes. The products at the cathode and anode are respectively:
(1) H2, O2
(2) O2, H2
(3) O2, Na
(4) O2, SO2