Van Arkel method of purification of metals involves converting the metal to a

1. Volatile compound

2. Volatile unstable compound

3. Non-volatile stable compound

4. Non-volatile unstable compound

Subtopic:  Refining Process |
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Which of the following is correct?

I.  G° for reaction (i) is more negative at T < 1125K

II.  G° for the reduction of CO is more negative at T < 1125K

III.  H2 is a better reducing agent at T < 1125K

IV.  H2 is a better reducing agent at T > 1125K

1.  I and II

2.  I and III

3.  III only

4.  I and IV

Subtopic:  Ellingham Diagram |
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Which of the following reactions is an example of auto reduction?

1.  Fe3O4  + 4CO  3Fe + 4CO2 

2.  Cu2O + C  2Cu + CO

3.  Cu2+ (aq) + Fe (s)  Cu (s) + Fe2+(aq) 

4.  Cu2O + 12 Cu2S  3Cu + 12 SO2

Subtopic:  Metallurgy of individual elements |
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A number of elements are available in earth’s crust but most abundant elements are ____________.

1.  Al and Fe

2.  Al and Cu

3.  Fe and Cu

4.  Cu and Ag

Subtopic:  Intro - Flux, Leaching, Roasting & Calcination |
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Zone refining is based on the principle that ___________.
 

1.  Impurities of low boiling metals can be separated by distillation.
2.  Impurities are more soluble in molten metal than in solid metal.
3.  Different components of a mixture are differently adsorbed on an adsorbent.
4.  Vapors of the volatile compounds can be decomposed in pure metal.

Subtopic:  Refining Process |
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In the metallurgy of aluminium ________________.

1. Al3+ is oxidized to Al(s).
2. Graphite anode is oxidized to carbon monoxide and carbon dioxide.
3. Oxidation state of oxygen changes in the reaction at the anode.
4. Oxidation state of oxygen changes in the overall reaction involved in the process.

Subtopic:  Metallurgy of individual elements |
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Electrolytic refining is used to purify which of the following metals?

1.  Cu and Zn

2.  Ge and Si

3.  Zr and Ti

4.  Zn and Hg

Subtopic:  Refining Process |
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Answer the question on the basis of Figure

Choose the correct option of temperature at which carbon reduces FeO to iron and produces CO.

1.  Below temperature at point A.

2.  Approximately at the temperature corresponding to point A.

3.  Above temperature at point A but below the temperature at point D.

4.  Above temperature at point A.

Subtopic:  Ellingham Diagram |
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Match the items of Column I with items of Column II and assign the correct code:

         Column I            Column II

(A) Pendulum         (1) Chrome steel

(B) Malachite          (2) Nickel steel

(C) Calamine          (3) Na3AlF6

(D) Cryolite            (4) CuCO3.Cu (OH)2

                             (5) ZnCO3

1.  A (1)  B (2)  C (3)  D (4)

2.  A (2)  B (4)  C (5)  D (3)

3.  A (2)  B (3)  C (4)  D (5)

4.  A (4)  B (5)  C (3)  D (2)

Subtopic:  Intro - Flux, Leaching, Roasting & Calcination |
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Match the items of Column I with the items of Column II and assign the correct
code :

Column I Column II
(A) Colored bands  (1) Zone refining
(B) Impure metal to volatile complex  (2) Fractional distillation
(C) Purification of Ge and Si    (3) Mond Process
(D) Purification of mercury  (4) Chromatography
(5) Liquation

1. A =(1); B=(2); C=(4); D=(5)

2. A=(4); B=(3); C=(1); D=(2)

3. A=(3); B=(4); C=(2); D=(1)

4. A=(5); B=(4); C=(3); D=(2)

Subtopic:  Refining Process |
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