The resistance of a cell containing 0.001 M KCl solution at 298 K is 1500 . The conductivity is 0.146 × 10–3 S cm–1The cell constant would be-

1. 0.12 cm-1 2. 0.56 cm-1
3. 0.22 cm-1 4. 1.36 cm-1

Subtopic:   Kohlrausch Law & Cell Constant |
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The number of Faradays required to produce 20.0 g of Ca from molten CaCl2 is-

1. 2F

2. 1F

3. 4F

4. 3F

Subtopic:  Faraday’s Law of Electrolysis |
 77%
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Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3, and CuSO4, respectively are connected in series.

A steady current of 1.5 amperes was passed through them until 1.45 g of silver was deposited at the cathode of cell B. The current flow time is-

1. 14 minutes

2. 25 minutes

3. 20 minutes

4. 11 minutes

Subtopic:  Faraday’s Law of Electrolysis |
 62%
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If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?

1. 2.35 × 10-22
2. 2.25 × 1022
3. 1.34 × 1021
4. 3.16 × 1024

Subtopic:  Faraday’s Law of Electrolysis |
 81%
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What is the quantity of electricity in coulombs needed to reduce 1 mol of Cr2O72-? Consider the reaction: Cr2O72- + 14H+ +6e-   2Cr+3 + 7H2O

1. 578992 C

2. 289461 C

3. 192974 C

4. 96487 C

Subtopic:  Faraday’s Law of Electrolysis |
 68%
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What is the potential of hydrogen electrode in contact with a solution whose pH is 10?

1. 0.591 V

2. -0.591 V

3. 0.295 V

4. -0.295 V

Subtopic:  Nernst Equation |
 71%
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What will be the emf of the cell in which the following reaction takes place? Given Ecell° = 1.05 V

Ni(s)+2Ag+(0.002 M) Ni2+(0.160 M) + 2Ag(s)

1. 0.80 V

2. 0.91 V

3. 0.45 V

4. 0.36 V

Subtopic:  Nernst Equation |
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The cell in which the following reactions occurs:

2Fe3+(aq)+2I-(aq)2Fe2+(aq)+I2(s) has  \(E_{cell}^{o}\) = 0.236 V at 298 K.

The equilibrium constant of the cell reaction is : 

1. 9.57 × 107
2. 8.43 × 106
3. 3.68 × 10-7
4. 1.74 × 105

Subtopic:  Relation between Emf, G, Kc & pH |
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The molar conductivity of 0.025 mol L−1 methanoic acid is 46.1 S cm2 mol−1.

What is the dissociation constant of methanoic acid? Given λ°(H+)= 349.6 S cm2 mol−1 and λ°(HCOO) = 54.6 S cm2 mol-1

1. 2.43 × 104 mol L-1
2. 1.15 × 10-5 mol L-1
3. 3.67 × 10-4 mol L-1
4. 2.44 × 10-6 mol L-1

Subtopic:  Conductance & Conductivity |
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Mg(s) | Mg2+(0.001M) || Cu2+(0.0001 M) | Cu(s)

EMg2+/Mgo=-2.36 V; ECu2+/Cuo=0.34V

The value of Ecell  for the above reaction is -

1. 3.46 V  2. 3.15 V
3. 2.67 V 4. 1.24 V
Subtopic:  Nernst Equation |
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