The shape of AsF5 is:
1. Pentagonal bipyramidal.
2. Trigonal bipyramidal.
3. Distorted tetrahedral.
4. Square pyramidal.
The incorrect statement about NH3 and H2O is :
1. The bond angle in NH3 is less than in H2O.
2. Both have distorted tetrahedral geometries.
3. The bond angle in H2O is less than in NH3.
4. Both are sp3 hybridized.
The relative order of stability of the following species: \(\mathrm{O}_2,\mathrm{O}^+_2,\mathrm{O}^-_2~\mathrm{and}~\mathrm{O}^{2-}_2\) is -
1. | \(\mathrm{O}^+_2>\mathrm{O}_2>\mathrm{O}^-_2>\mathrm{O}^{2-}_2\) | 2. | \(\mathrm{O}^{2-}_2>\mathrm{O}_2>\mathrm{O}^-_2>\mathrm{O}^{+}_2\) |
3. | \(\mathrm{O}_2>\mathrm{O}^+_2>\mathrm{O}^-_2>\mathrm{O}^{2-}_2\) | 4. | \(\mathrm{O}_2>\mathrm{O}^{2-}_2>\mathrm{O}^-_2>\mathrm{O}^{+}_2\) |
The plus and negative sign of the orbitals mean:
1. Wave function.
2. Probability density.
3. Quantum number of orbitals.
4. Frequency of orbitals.
The change in the hybridization of the Al atom in the above reaction is:
1. \(s p^{2} \text { to } s p^{3}\)
2. \(\mathrm{sp}^{3} \text { to } s p^{2}\)
3. \(\mathrm{sp}^{3} \text { to } \mathrm{dsp}{ }^{2}\)
4. \(\operatorname{sp}^{2} \text { to } d s p^{2}\)
Considering the X-axis as the internuclear axis, a sigma bond will not be formed in:
The set of oxides of nitrogen that are paramagnetic in nature is:
1. NO, N2O
2. N2O3, NO
3. NO, NO2
4. N2O, NO2
Which of the compounds given below will exhibit a linear structure?
1. NO2
2. HOCl
3. O3
4. N2O
Match the compounds of Xe in Column I with the molecular structure in Column II.
Column-I | Column-II | ||
(a) | XeF2 | (i) | Square planar |
(b) | XeF4 | (ii) | Linear |
(c) | XeO3 | (iii) | Square pyramidal |
(d) | XeOF4 | (iv) | Pyramidal |
(a) | (b) | (c) | (d) | |
1. | (ii) | (i) | (iii) | (iv) |
2. | (ii) | (iv) | (iii) | (i) |
3. | (ii) | (iii) | (i) | (iv) |
4. | (ii) | (i) | (iv) | (iii) |
Match the coordination number and type of hybridization with the distribution of hybrid orbitals in space based on Valence bond theory.
Coordination number and type of hybridisation | Distribution of hybrid orbitals in space | ||
(a) | 4, sp3 | (i) | Trigonal bipyramidal |
(b) | 4, dsp2 | (ii) | Octahedral |
(c) | 5, sp3d | (iii) | Tetrahedral |
(d) | 6, d2sp3 | (iv) | Square planar |
(a) | (b) | (c) | (d) | |
1. | (ii) | (iii) | (iv) | (i) |
2. | (iii) | (iv) | (i) | (ii) |
3. | (iv) | (i) | (ii) | (iii) |
4. | (iii) | (i) | (iv) | (ii) |