The electrophile involved in the above reaction is:
1. Dichloromethyl cation (CHCl2)
2. Dichlorocarbene (:CCl2)
3. Trichloromethyl anion (CCl3)
4. Formyl cation (CHO)

Subtopic:  Phenols: Preparation & Properties |
 82%
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In the given transformation, which of the following is the most appropriate reagent ?

(1) Zn-Hg/HCl

(2) Na, Liq. NH3

(3) NaBH4

(4) NH2NH2,OH

 

Subtopic:  Alcohols: Preparation & Properties |
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An unknown alcohol is treated with the “Lucas reagent” to determine whether the alcohol is primary, secondary or tertiary. Which alcohol reacts the fastest and by what mechanism:

1. secondary alcohol by SN2

2. tertiary alcohol by SN2

3. secondary alcohol by SN1

4. tertiary alcohol by SN1

Subtopic:  Alcohols: Preparation & Properties |
 77%
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Sodium phenoxide when heated with CO2 under pressure at 125°C yields a product which on acetylation produces C.

The major product C would be :

(1) 

(2) 

(3) 

(4) 

Subtopic:  Phenols: Preparation & Properties |
 62%
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A compound with molecular formula C4H10O3 is converted by the action of acetyl chloride to a compound with molar mass 190. The original compound has: 

(1) one OH group

(2) two OH groups

(3) three OH groups

(4) no OH group

Subtopic:  Alcohols: Preparation & Properties |
 62%
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Phenyl ethyl ether with concentrated hydrobromic acid on boiling yields:-

1. Phenol and ethyl bromide

2. Bromobenzene and ethanol

3. Phenol and ethane

4. Bromobenzene and ethane

Subtopic:  Ethers: Preparation & Properties, Uses |
 81%
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An organic compound A reacts with sodium metal and forms B. On heating with conc. H2SO4, A gives diethyl ether. So A and B are:
1. C3H7OH and CH3ONa
2. CH3OH and CH3ONa
3. C4H9OH and C4H9ONa
4. C2H5OH and C2H5ONa

Subtopic:  Alcohols: Preparation & Properties | Mechanism of Dehydration, Methanol & Ethanol |
 80%
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Which will form two oximes with NH2OH?

(1) CH3COCH3

(2) CH3CH2COCH3

(3) CH3CH2COCH2CH3

(4) 

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
 60%
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Identify A, X, Y and Z 

(1) A-methoxymethane, X-ethanoic acid, Y-acetate ion, Z-hydrazine

(2) A- methoxymethane, X-ethanol, Y-ethanoic acid, Z- semicarbazide

(3) A-Acetaldehyde, X-ethanol, Y-but-2-en-1-ol, Z- semicarbazone

(4) A-ethanol, X-acetaldehyde, Y-butanone, Z-hydrazone

Subtopic:  Alcohols: Preparation & Properties |
 70%
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Reaction of phenol with chloroform in the presence of dilute sodium hydroxide finally

introduces, which one of the following functional group?

1. -CH2Cl                       

2. -COOH

3. -CHCl2                       

4. -CHO

Subtopic:  Phenols: Preparation & Properties |
 71%
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