The temperature dependent term among the following is -
1. | Molality | 2. | Molarity |
3. | Mole fraction | 4. | Weight percentage |
The van't Hoff factor [i] for a dilute aqueous solution of the strong electrolyte barium hydroxide is?
(1) 0
(2) 1
(3) 2
(4) 3
Which one of the following is incorrect for ideal solution ?
(1)
(2)
(3)
(4)
At 100°C the vapour pressure of a solution of 6.5 g of a solute in 100 g water is 732 mm. If Kb = 0.52, the boiling point of this solution will be
(1) 100°C
(2) 102°C
(3) 103°C
(4) 101°C
Which of the following statements about the composition of the vapour over an ideal 1:1
molar mixture of benzene and toluene is correct? Assume that the temperature is
constant at 25°C.
(Given, vapour pressure data at 25°C, benzene = 12.8 kPa, toluene = 3.85 kPa)
1. The vapour will contain a higher percentage of toluene
2. The vapour will contain equal amounts of benzene and toluene
3. Not enough information is given to make a prediction
4. The vapour will contain a higher percentage of benzene
Which one is not equal to zero for an ideal solution?
1. ΔHmix
2. ΔSmix
3. ΔVmix
4. ΔP=PObserved-PRaoult
Which one of the following elctrolytes has the same value of van't Hoff's factor(i) as
that of Al2(SO4)3 (if all are 100% ionised)?
1. K2SO4
2. K3[Fe(CN)6]
3. Al(NO3)3
4. K4[Fe(CN)6]
Of the following 0.10 m aqueous solutions, which one will exhibit the largest freezing
point depression?
1. KCl
2. C6H12O6
3. Al2(SO4)3
4. K2SO4
pA and pB are the vapour pressure of pure liquid components, A and B, respectively of an
ideal binary solution.If x, represents the mole fraction of component A, the total pressure
of the solution will be.
1. pA + xA(pB-pA)
2. pA + xA(pA-pB)
3. pB + xA(pB-pA)
4. pB + xA(pA-pB)
The freezing point depression constant format is -1.86°C m-1. If 5.00g Na2SO4 dissolved
in 45.0 g H2O, the freezing point is changed by -3.82°C. Calculate the van't Hoff factor
for NaSO4
1. 2.63
2. 3.11
3. 0.381
4. 2.05