The percentage of copper in a copper(II) salt can be determined by using a thiosulphate titration. 0.305 gm of a copper(II) salt was dissolved in water and added to, an excess of potassium iodide solution liberating iodine according to the following equation 2Cu2 (aq) + 4I– (aq) 2CuI(s) + I2(aq) The iodine liberated required 24.5cm3 of a 0.100 mole dm-3 solution of sodium thiosulphate 2S2O32- (aq) + I2(aq) 2I– (aq) + S4O62- (aq) the percentage of copper, by mass in the copper(ll) salt is. [Atomic mass of copper = 63.5]
1. 64.2
2. 51.0
3 48.4
4. 25.5
Oxygen contains 90% O16 and 10% O18. Its atomic mass is
(1) 17.4
(2) 16.2
(3) 16.5
(4) 17
The total number of electrons present in 1.6 gm. of methane is [IIT 1976; Roorkee 1985; CPMT 1987, 92]
(1) 6.02 × 1023
(2) 6.02 × 1022
(3) 6.02 × 1021
(4) 4.02 × 1020
KClO3 on heating decomposes to KCl and O2. The volume of O2 at STP liberated by 0.1 mole KClO3 is
1. 4.36 L
2. 3.36 L
3. 2.36 L
4. None of these
At S.T.P. the density of CCl4 vapour in g/L will be nearest to [CBSE PMT 1988]
(1) 6.84
(2) 3.42
(3) 10.26
(4) 4.57
4.4 g of an unknown gas occupies 2.24 litres of volume at NTP. The gas may be:
1. | Carbon dioxide | 2. | Carbon monoxide |
3. | Oxygen | 4. | Sulphur dioxide |
The number of gram molecules of oxygen in 6.02 × 1024 CO molecules are:
1. 10 g molecules
2. 5 g molecules
3. 1 g molecules
4. 0.5 g molecules
The mass of carbon present in 0.5 mole of K4[Fe(CN)6] is:
1. 1.8 g
2. 18 g
3. 3.6 g
4. 36 g
The number of moles of BaCO3 which contains 1.5 moles of oxygen atoms is:
1. 0.5
2. 1
3. 3
4. 6.02 ×1023
The oxide of metal contains 40% by mass of oxygen. The percentage of chlorine in the chloride of the metal is
1. 84.7
2. 74.7
3. 64.7
4. 44.7