If molality of the dilute solution is doubled, the value of molal depression constant (K_f) will be?

(1) doubled

(2) halved

(3) tripled

(4) unchanged

The temperature dependent term among the following is -

The van't Hoff factor [i] for a dilute aqueous solution of the strong electrolyte barium hydroxide is?

(1) 0

(2) 1

(3) 2

(4) 3

Which one of the following is incorrect for ideal solution ?

(1) $∆{\mathrm{H}}_{\mathrm{mix}}=0$

(2) $∆{\mathrm{U}}_{\mathrm{mix}}=0$

(3) $∆\mathrm{P}={\mathrm{P}}_{\mathrm{obs}}-{\mathrm{P}}_{\mathrm{calculated} \mathrm{by} \mathrm{Raoul}\text{'}\mathrm{s} \mathrm{law}} = 0$

(4) $∆{\mathrm{G}}_{\mathrm{mix}}=0$

At 100°C the vapour pressure of a solution of 6.5 g of a solute in 100 g water is 732 mm. If K_b = 0.52, the boiling point of this solution will be

(1) 100°C

(2) 102°C

(3) 103°C

(4) 101°C

Which of the following statements about the composition of the vapour over an ideal 1:1

molar mixture of benzene and toluene is correct? Assume that the temperature is

constant at 25°C.

(Given, vapour pressure data at 25°C, benzene = 12.8 kPa, toluene = 3.85 kPa)

1. The vapour will contain a higher percentage of toluene

2. The vapour will contain equal amounts of benzene and toluene

3. Not enough information is given to make a prediction

4. The vapour will contain a higher percentage of benzene

Which one is not equal to zero for an ideal solution?

1. ΔH_mix 

2. ΔS_mix

3. ΔV_mix

4. ΔP=P_Observed-P_Raoult

Which one of the following elctrolytes has the same value of van't Hoff's factor(i) as

that of Al₂(SO₄)₃  (if all are 100% ionised)? 

1. K₂SO₄

2. K₃[Fe(CN)₆]

3. Al(NO₃)₃

4. K₄[Fe(CN)₆]

Of the following 0.10 m  aqueous solutions, which one will exhibit the largest freezing

point depression?

1. KCl

2. C₆H₁₂O₆

3. Al₂(SO₄)₃

4. K₂SO₄

p_A and p_B are the vapour pressure of pure liquid components, A and B, respectively of an

ideal binary solution.If x, represents the mole fraction of component A, the total pressure

of the solution will be.

1. p_A + x_A(p_B-p_A)

2. p_A + x_A(p_A-p_B)

3. p_B + x_A(p_B-p_A)

4. p_B + x_A(p_A-p_B)