Consider the following sets of quantum numbers:
Which of the following sets of quantum numbers is not possible?
1. ii, iii, and iv
2. i, ii, iii, and iv
3. ii, iv and v
4. i and iii
According to the Bohr Theory, which of the following transitions in the hydrogen atom will give rise to the least energetic photon?
1. n = 5 to n = 3
2. n = 6 to n = 1
3. n = 5 to n = 4
4. n = 6 to n = 5
If the energy value is E = 3.03 × 10–19 Joules, (h = 6.6×10–34 J x sec., C = 3×108 m/sec), then the value of the corresponding wavelength is:
1. | 65.3 nm | 2. | 6.53 nm |
3. | 3.4 nm | 4. | 653 nm |
Uncertainty in position of a and He is similar. If uncertainty in momentum of is , then uncertainty in momentum of He will be:
1. | 32 × 105 | 2. | 16×105 |
3. | 8 × 105 | 4. | None of the above |
Assertion (A): | Half-filled and fully-filled degenerate orbitals are more stable. |
Reason (R): | Extra stability is due to the symmetrical distribution of electrons and high exchange energy. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Which of the following options does not represent ground state electronic configuration of an atom?
1.
2.
3.
4.
Match the ensuing rules with the corresponding statements:
Rules | Statements | ||
A. | Hund’s Rule | 1. | No two electrons in an atom can have the same set of four quantum numbers. |
B. | Aufbau Principle | 2. | Half-filled and completely filled orbitals have extra stability. |
C. | Pauli's Exclusion Principle | 3. | Pairing of electrons in the orbitals belonging to the same subshell does not take place until each orbital is singly occupied. |
D. | Heisenberg’s Uncertainty Principle | 4. | It is impossible to determine the exact position and exact momentum of a subatomic particle simultaneously. |
5. | In the ground state of atoms, orbitals are filled in the order of their increasing energies. |
A | B | C | D | |
1. | 3 | 5 | 1 | 2 |
2. | 1 | 2 | 3 | 4 |
3. | 3 | 5 | 1 | 4 |
4. | 4 | 5 | 3 | 2 |
The radii of the first bohr orbit of H(rH), He+ (rHe+) and Li2+(rLi2+) are in the order:
1. rH = rHe+ = rLi+2
2. rH < rHe+ < rLi2+
3. rH > rHe+ > rLi2+
4. rHe+ < rH < rLi2+
A 100-watt bulb emits monochromatic light of wavelength 400 nm. The number of photons emitted per second by the bulb is :
1. 4
2.
3.
4. 2