The nitration of aniline in a strong acidic medium results in the formation of m-nitroaniline because:
1. | In spite of substituents, the nitro group always goes to only the m-position. |
2. | In electrophilic substitution reactions, the amino group is meta-directive. |
3. | In the absence of substituents, the nitro group always goes to only m-position. |
4. | In an acidic (strong) medium, aniline is present as an anilinium ion. |
Propanoic acid gives a series of reactions as given below.
The structure of D would be:
1.
2.
3.
4.
D is N-methyl aniline in the given below sequence of reaction:
\(\text A\xrightarrow{\bf\text{ reduction }}\text B\xrightarrow{\bf\text {CHCl}_3\text{/KOH}}\text C\xrightarrow{\bf\text{ reduction }}\text D\)
Structure of A can be:
1. | ![]() |
2. | ![]() |
3. | \(\mathrm{CH_3NH_2 }\) |
4. | ![]() |
Column I | Column II | ||
a. | |
(i) | Carbylamine reaction |
b. | |
(ii) | Gatterman reaction |
c. | |
(iii) | Hoffmann Bromamide degradation reaction |
d. | |
(iv) | Sandmeyer reaction |
I. | ![]() |
II. | \(\mathrm{(CH_3)_2NH }\) |
III. | ![]() |
Assertion (A): | Reduction of nitrobenzene using Fe and HCl is preferred over Sn and HCl. |
Reason (R): | With Fe, only a small amount of HCl is required to initiate the reaction, as FeCl2 formed gets hydrolyzed to release hydrochloric acid. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | Primary aliphatic amines react with nitrous acid and liberate nitrogen gas quantitatively. |
Reason (R): | The quantitative evolution of nitrogen is used in the estimation of amino acids and proteins. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
'A' and 'B' in the following reactions are:
A | B | A | B | ||
1. | ![]() |
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2. | ![]() |
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3. | ![]() |
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4. | ![]() |
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