Identify correct match using Column I & Column II
Column I Column II
(i) Spontaneous process (a) Isothermal and isobaric process
(ii) \(\Delta H^\circ\) (b) \(\Delta H<0 \)
(iii) \(\Delta T=0, \Delta P=0 \) (c) \(\Delta G<0 \)
(iv) Exothermic process (d) (Bond energy of reactant) - (Bond energy of product)
 
I II III IV
1. c d a b
2. b a c d
3. d b c d
4. a d b c
Subtopic:  First Law of Thermodynamics | Spontaneity & Entropy | Gibbs Energy Change |
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3 moles of helium gas at 1 bar is compressed reversibly and isothermally at 400 K to 10 bar pressure. The work done (in J) on the system is: (Given: \(R= 8.314 ~J K^{-1}~ mol^{-1}\) )
1. \(2.29 \times 10^4 \) 2. \(2.29 \times 10^{-4} \)
3. \(-2.29 \times 10^4 \) 4. \(-2.29 \times 10^{-4} \)
Subtopic:  First Law of Thermodynamics |
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1 mol of monoatomic ideal gas expanded adiabatically against a constant pressure of 2 atm from 10L to 20L. The correct option for the above process is:

1. q = 20 L-atm 
2. \(\Delta U = 0 \)
3. \(\Delta U = -20 ~\text L~\text {atm} \)
4. \(\text w = 10 ~\text L~ \text {atm} \)
Subtopic:  First Law of Thermodynamics |
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