Given lanthanoid ions ,the tendency to form the complexes is highest for:
1. Ce+3
2. Pm+2
3. Lu+3
4. Eu+2
When neutral or faintly alkaline is treated with potassium iodide, iodide ion is converted into 'X'. 'X' is:
1.
2.
3.
4.
A colored ion in aqueous solutions among the following is:
1. La3+ (Z=57)
2. Ti3+ (Z=22)
3. Lu3+ (Z=71)
4. Sc3+ (Z=21)
Four statements for Cr and Mn are given below:
(I) | Cr2+ and Mn3+ have the same electronic configuration. |
(II) | Cr2+ is a reducing agent while Mn3+ is an oxidizing agent. |
(III) | Cr2+ is an oxidizing agent while Mn3+ is a reducing agent. |
(IV) | Both Cr and Mn are oxidizing agents. |
The correct statements are
1. (I), (III),(IV)
2. (I) , (II)
3. (I), (II) and (IV)
4. (I), (IV)
oxidised product of X
X in the above reaction can not be:
1.
2.
3.
4.
Identify the incorrect statement.
1. | The transition metals and their compounds are known for their catalytic activity due to their ability to adopt multiple oxidation states and to form complexes. |
2. | Interstitial compounds are those that are formed when small atoms like H, C or N are trapped inside the crystal lattices of metals. |
3. | The oxidation states of chromium in CrO42– and Cr2O72– are not the same. |
4. | Cr2+(d4) is a stronger reducing agent than Fe2+(d6) in water. |
Urea reacts with water to form A which will decompose to form B. B when passed through \(\left(Cu\right)^{2 +}\) (aq), deep blue colour solution C is formed. What is the formula of C from the following?
1. | \(\left[Cu \left(NH_{3}\right)_{4}\right]^{2 +}\) | 2. | \(Cu \left(\right. OH \left.\right)_{2}\) |
3. | \(CuCO_{3} . Cu (OH)_{2}\) | 4. | \(CuSO_{4}\) |
The manganate and permanganate ions are tetrahedral, due to:
1. | The π-bonding involves the overlap of d-orbitals of oxygen with d-orbitals of manganese. |
2. | The π-bonding involves the overlap of p-orbitals of oxygen with d-orbitals of manganese. |
3. | Absence of π-bonding. |
4. | The π-bonding involves the overlap of p-orbitals of oxygen with p-orbitals of manganese. |
1. | The greater metallic character of the lanthanoids than that of the corresponding actinoids. |
2. | More energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals. |
3. | The lesser energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals. |
4. | More active nature of the actinoids. |