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List-I (Mixtures/Sample) |
List-II (Technique used for purification) |
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A. | Glycerol from spent lye | (I) | Steam distillation |
B. | Chloroform + Aniline | (II) | Fractional distillation |
C. | Fractions of crude oil | (III) | Distillation under reduced pressure |
D. | Aniline+water | (IV) | Distillation |
Options: | (A) | (B) | (C) | (D) |
1. | III | IV | II | I |
2. | IV | II | I | III |
3. | I | II | III | IV |
4. | I | III | II | IV |
Statement I: | In an organic compound, when inductive and electromeric effects operate in opposite directions, the inductive effect predominates. |
Statement II: | Hyperconjugation is observed in o-xylene. |
I: | These compounds may have different carbon skeletons. |
II: | Chemical properties are altered due to the differences in functional groups. |
III: | Functional groups may occupy different positions on the carbon skeleton. |
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3. | 4. |
\(\mathrm{CH_3-CH_3, \ CH_3-CH_2-CH_3, \ }\)
\(\mathrm{\left(CH_3\right)_2 CH-CH_3, }\) and \(\mathrm{CH_3-CH_2-CH\left(CH_3\right)_2 }\)
The increasing order of stability of the free radicals formed from homolytic fission of the above three alkanes is:
1. | \(\mathrm{ (CH_3)_2 \dot{C}-CH_2 CH_3<CH_3-\dot{C} H-CH_3 \\ <CH_3-\dot{C} H_2<(CH_3)_3 \dot{C} }\) |
2. | \( \mathrm{CH_3-\dot{C} H_2<CH_3-\dot{C} H-CH_3 \\ <\left(CH_3\right)_2 \dot{C}-CH_2 CH_3<\left(CH_3\right)_3 \dot{C}}\) |
3. | \(\mathrm{CH_3-\dot{C} H_2<CH_3-\dot{C} H-CH_3\\ <\left(CH_3\right)_3 \dot{C}<\left(CH_3\right)_2 \dot{C}-CH_2 CH_3 }\) |
4. | \(\mathrm{ \left(CH_3\right)_3 \dot{C}<\left(CH_3\right)_2 \dot{C}-CH_2-CH_3 \\ <CH_3-\dot{C} H-CH_3<CH_3-\dot{C} H_2 }\) |