Cyanohydrin of 'X' gives lactic acid on hydrolysis. The compound 'X' will be:

1. Acetone                                 

2. Acetaldehyde

3. Propanal                                 

4. HCHO

Subtopic:  Isomers & Reaction Mechanism |
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Oxalic acid on treatment with conc. H2SO4 gives:

1. CO + H2O2                           

2.  H2O +CO+CO2

3. HCOOH + CO2                       

4.  HCOOH + CO2 +O2

Subtopic:  Carboxylic Acids: Preparation & Properties |
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Aldehydes and ketones will not form crystalline derivatives with                   

1. Sodium bisulphite

2. Phenyl hydrazine

3. Semicarbazide hydrochloride

4. Dihydrogen sodium phosphate

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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Which one of the following compounds on treatment with LiAlH4 will give a product that will give a positive iodoform test?

1. CH3CH2CHO                             

2. CH3CH2COOCH3

3. CH3CH2OCH2CH                     

4. CH3COCH3

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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In this reaction,

\(CH_{3}CHO \ + \ HCN \ \xrightarrow[]{} \ CH_{3}CH(OH)CN \ \xrightarrow[]{\textbf{H.OH}} \\ CH_{3}CH(OH)COOH\)

an asymmetric compound is generated. The acid obtained would be:        

1. 50% D + 50% L-isomer

2. 20% D + 80% L-isomer

3. D-isomer

4. L-isomer

Subtopic:  Isomers & Reaction Mechanism |
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Which of the following has most acidic hydrogen?

1. 3-hexanone                         

2. 2,4-hexanedione

3. 2,5-hexanedione                   

4. 2,3-hexanedione

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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Acetaldehyde reacts with                

1. Only electrophiles

2. Only nucleophiles

3. Only free radicals

4. Both electrophiles and nucleophiles

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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Which compounds will not reduce Fehling's solution?

1. Methanal                                 

2. Ethanal

3. Trichloroethanal                       

4. Benzaldehyde

 

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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Fehling's solution is:

1. Acidified copper sulphate solution

2. Ammoniacal cuprous chloride solution

3. Copper sulphate, Rochelle salt + NaOH

4. None of the above

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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Benzaldehyde and acetaldehyde can be distinguished by:

1. Iodoform test

2. 2:4 DNP test

3. NH3 reaction

4. Wolff-Kishner's reduction

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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