A mixture of benzaldehyde and formaldehyde on heating with aqueous (conc.)NaOH solution gives

1. Benzyl alcohol and sodium formate

2. Sodium benzoate and methyl alcohol

3. Sodium benzoate and sodium formate

4. None of the above

Subtopic:  Name Reaction |
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Ethyl acetate on reaction with excess of methyl magnesium chloride and dil. H2SO4 gives-

1. Dimethyl ketone

2. Iso-propyl alcohol

3. Ethyl aceto acetate

4. t-Butyl alcohol

Subtopic:  Acid Derivatives - Preparation, Properties & Uses |
 51%

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Cyanohydrin of 'X' gives lactic acid on hydrolysis. The compound 'X' will be:

1. Acetone                                 

2. Acetaldehyde

3. Propanal                                 

4. HCHO

Subtopic:  Isomers & Reaction Mechanism |
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Oxalic acid on treatment with conc. H2SO4 gives:

1. CO + H2O2                           

2.  H2O +CO+CO2

3. HCOOH + CO2                       

4.  HCOOH + CO2 +O2

Subtopic:  Carboxylic Acids: Preparation & Properties |
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Aldehydes and ketones will not form crystalline derivatives with                   

1. Sodium bisulphite

2. Phenyl hydrazine

3. Semicarbazide hydrochloride

4. Dihydrogen sodium phosphate

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
 60%
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Which one of the following compounds on treatment with LiAlH4 will give a product that will give a positive iodoform test?

1. CH3CH2CHO                             

2. CH3CH2COOCH3

3. CH3CH2OCH2CH                     

4. CH3COCH3

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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In this reaction,

\(CH_{3}CHO \ + \ HCN \ \xrightarrow[]{} \ CH_{3}CH(OH)CN \ \xrightarrow[]{\textbf{H.OH}} \\ CH_{3}CH(OH)COOH\)

an asymmetric compound is generated. The acid obtained would be:        

1. 50% D + 50% L-isomer

2. 20% D + 80% L-isomer

3. D-isomer

4. L-isomer

Subtopic:  Isomers & Reaction Mechanism |
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Which of the following has most acidic hydrogen?

1. 3-hexanone                         

2. 2,4-hexanedione

3. 2,5-hexanedione                   

4. 2,3-hexanedione

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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Acetaldehyde reacts with                

1. Only electrophiles

2. Only nucleophiles

3. Only free radicals

4. Both electrophiles and nucleophiles

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
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Which compounds will not reduce Fehling's solution?

1. Methanal                                 

2. Ethanal

3. Trichloroethanal                       

4. Benzaldehyde

 

Subtopic:  Aldehydes & Ketones: Preparation & Properties |
 80%
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